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2 edition of X-ray diffraction studies of short range ordering in amorphous polymers. found in the catalog.

X-ray diffraction studies of short range ordering in amorphous polymers.

Geoffrey William Longman

X-ray diffraction studies of short range ordering in amorphous polymers.

by Geoffrey William Longman

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  • 38 Currently reading

Published in Bradford .
Written in English


Edition Notes

Ph.D. thesis. Typescript.

SeriesTheses / University of Bradford Postgraduate School of Studies in Polymer Science
The Physical Object
Pagination133p.
Number of Pages133
ID Numbers
Open LibraryOL13784712M

This book presents the basic theories underlying x-ray and neutron scattering, as well as the various techniques that have been developed for their application to the study of polymers. The two scattering methods are discussed together from the beginning, so as to allow readers to gain a unified view of the scattering phenomena. The structures of Al-Ni melts with 0, 10, 18, 25, 28, 32, 40, 75, 90, and at % Ni are studied by X-ray diffraction. The structural models of the melts, which were analyzed by the Voronoi-Delaunay transformation method, are reconstructed by a procedure that is inverse to the Monte Carlo method using experimental structure-factor curves. The parameters characterizing atomic ordering at short.

  The authors set forth a variety of tested and proven methods for analyzing ordered and disordered structures in polymer crystals, including X-ray diffraction, electron diffraction, and microscopy. In addition to the basics, the book explores several advanced and emerging topics in the field such as symmetry breaking, frustration, and the.   Table 1 summarizes experimental values of q 1 for a variety of metallic glasses, determined from neutron and X-ray diffraction studies in the present work and in the literature 4,17,18,19,20,21,

  In region IV, the polymers are packed in a bulk-like state, and deform like a glassy material; 30 the differential scanning calorimetry (DSC) and X-ray diffraction (XRD) data have shown that these polymers are amorphous in bulk state. 13,24 This is consistent with our conclusions from the analysis of the isotherms that the polymer, although.   A recent book deals with applications of x-ray and neutron scattering methods to polymer science In all materials the existence of chemical bonding will give rise to short-range and intermediate-range structural order but not to long-range periodic order as in the case of Early x-ray diffraction studies on polyatomic glasses.


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X-ray diffraction studies of short range ordering in amorphous polymers by Geoffrey William Longman Download PDF EPUB FB2

In the present study, X-ray diffraction and Raman spectroscopic techniques have been used to develop a new method for analyzing short-range molecular order in amorphous starch. The study was performed using wheat and potato starches that were gelatinized by heating at °C in various mixtures of between and starch and water.

: Xia Liu, Huiyu Luan, Yu Jinglin, Shuo Wang, Shujun Wang, Les Copeland. The study of short-range order of glassy polymers is concerned with structural arrangements in a polymer glass on length scales, which directly involve the atomistic chemical detail of the polymer, and which extend to include the chain segment and its interaction with other chain segments.

A chain segment is a conceptual object that may be. Some polymers (e.g., polyethylene) can have macromolecules efficiently packed in some regions, producing a higher degree of long-range order (i.e., crystalline region), and in other regions macromolecules have a short-range order (i.e., amorphous region), as reported in Fig.

fingerprinting of amorphous and nano materials and to study the short range order (i.e. inter-atomic distances) of the material. The PDF technique utilizes a Fourier transformation of the X-ray powder diffraction (XRPD) data and gives information about the inter-atomic distances of the material.

The. Conversely, Amorphous phase being of short order shows hump in XRD [broad range]. Crystaline material containing amorphous impurity could be easily identified using Xray. of amorphous APIs for drug products is the lack of reliable methods for structural characterization and fingerprinting.

The Atomic Pair distribution function (PDF) have been suggested as an alternative approach for fingerprinting of amorphous materials and to study the short range order (i.e.

inter-atomic distances) of the material. Short range order of amorphous solids and liquids give very broad diffraction peaks because there is a range of interatomic distances.

"Neutron and x-ray diffraction studies of liquids and. X-ray Diffraction Study of the Structure of Glass. Warren; Cite this: Chem. Rev. 26, On Amorphous Materials as Potential Objects in Solid-State NMR Studies. , Short range antiferromagnetic ordering in vitreous Fe2O3 P2O5.

Diffraction Analysis of Amorphous Materials Glasses and Polymers. by Diffraction of Polarized Neutrons. Matz, J. Kulda, P. Mikula. Pages Neutron-Diffraction Investigation of the Short-Range Atomic Order in Tellurite Glasses.

Neov, I. Gerasimova, P. Mikula X-Ray Diffraction Studies of Interdiffusion in Solid Solutions of A. The purpose of this paper is to provide a physical description of the amorphous state for pharmaceutical materials and to investigate the pharmaceutical implications.

Techniques to elucidate structural differences in pharmaceutical solids exhibiting characteristic X-ray amorphous powder patterns are also presented.

The X-ray amorphous powder diffraction patterns of microcrystalline. Studies of short-range order in amorphous polymers by radial distribution functions derived from X-ray diffraction.

[38] [39][40] Upon annealing the NDs at °C for 10 minutes in a vacuum, the diamond X-ray diffraction peak disappears with the emergence of sp 2 carbon structure peak. 41 The crystal lattice. Short-range order in amorphous material.

Source: Reproduced with permission from Bates S, Zografi G, Engers D, Morris K, Crowley K, Newman A. Analysis of amorphous and nanocrystalline solids from their X-ray diffraction patterns. Pharm Res ;23(10)– X-ray diffraction is used most frequently to investigate the structure of biocomposites with embedded nanostructure.

The XRD spectra of GOnPs sheet showed (Fig. A) the characteristic GOnPs peak appearing at 2θ= degrees, corresponding to a lattice d-spacing of the GOnPs-PCL meshes, an XRD peak (Fig. B) appeared at degrees representing the crystalline phase of. The different amorphous phases can have different short-range order or arrangement.

This type of analysis can be done in-house but we normally use. X-ray diffraction study of amorphous alloys Al–Ni–Ce–Sc with using Ehrenfest’s formula changing the type of short-range order.

A splitting the first peak of the function of radial atom. The structure of hydrous amorphous SiO2 is fundamental in order to investigate the effects of water on the physicochemical properties of oxide glasses and magma. The hydrous SiO2 glass with 13 wt.% D2O was synthesized under high-pressure and high-temperature conditions and its structure was investigated by small angle X-ray scattering, X-ray diffraction, and neutron diffraction experiments at.

Measurement and Modeling of Short and Medium Range Order in Amorphous Ta 2 O 5 Temperatures in Thin Polymer Films: Surface Effect or Artifact.

A High Energy X-ray Diffraction Study. X-ray diffraction has been a standard technique for investigating structural properties of materials.

However, most common applications in the organic materials community have been restricted to either chemical identification or qualitative strain analysis.

Moreover, its use for polymeric thin films has been challenging because of the low structure factor of carbon and the thin film nature of. X-ray diffraction studies of short range ordering in amorphous polymers Author: Longman, G. ISNI: Awarding Body: University of Bradford Current Institution: University of Bradford Date of Award: Availability of Full Text.

A Shimadzu XRD X-ray powder diffractometer (Shimadzu, Japan) coupled with a standard Cu sealed X-ray tube with voltage, current (40 kV and 40 mA), was used to characterize the amorphous or. X-ray diffraction procedures for polycrystalline and amorphous materials. 2nd ed. Wiley, New York.

Moore, D. M. and R. C. Reynolds, Jr. X-Ray diffraction and the identification and analysis of clay minerals. 2nd Ed.X-ray diffraction is a useful and powerful analysis technique for characterizing crystalline materials commonly employed in MSE, physics, and chemistry.

This informative new book describes the principles of X-ray diffraction and its applications to materials characterization. It consists of three parts.